1. Oxidation is defined as a process involving:
A. Loss of electrons
B. Gain of electrons
C. Gain of hydrogen
D. Decrease in oxidation number
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Answer: A. Loss of electrons
Explanation: According to the electronic concept, oxidation involves loss of electrons leading to an increase in oxidation state.
2. What is the oxidation number of Manganese (Mn) in KMnO₄?
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Answer: A. +7
Explanation: In KMnO₄: (+1) + x + 4(-2) = 0 ⇒ x - 7 = 0 ⇒ x = +7.
3. What is the oxidation number of Chromium (Cr) in K₂Cr₂O₇?
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Answer: A. +6
Explanation: In K₂Cr₂O₇: 2(+1) + 2x + 7(-2) = 0 ⇒ 2x - 12 = 0 ⇒ x = +6.
4. Reduction involves which of the following changes?
A. Gain of electrons
B. Loss of electrons
C. Increase in oxidation number
D. Loss of hydrogen
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Answer: A. Gain of electrons
Explanation: Reduction is defined as the process in which an atom or ion gains one or more electrons.
5. An oxidizing agent is a substance that:
A. Accepts electrons and gets reduced
B. Loses electrons and gets oxidized
C. Increases its own oxidation number
D. Donates protons
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Answer: A. Accepts electrons and gets reduced
Explanation: An oxidizing agent causes another species to lose electrons by accepting those electrons itself.
6. What is the oxidation number of Sulfur (S) in H₂SO₄?
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Answer: A. +6
Explanation: In H₂SO₄: 2(+1) + x + 4(-2) = 0 ⇒ x - 6 = 0 ⇒ x = +6.
7. Oxidation state of Oxygen in Hydrogen Peroxide (H₂O₂) is:
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Answer: A. -1
Explanation: Peroxides contain an O-O single bond, assigning an oxidation state of -1 to each oxygen atom.
8. A reaction in which the same species undergoes oxidation as well as reduction is called:
A. Disproportionation reaction
B. Displacement reaction
C. Combination reaction
D. Decomposition reaction
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Answer: A. Disproportionation reaction
Explanation: In a disproportionation reaction, an element in one oxidation state is simultaneously oxidized and reduced.
9. What is the oxidation number of Phosphorus (P) in H₃PO₄?
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Answer: A. +5
Explanation: In H₃PO₄: 3(+1) + x + 4(-2) = 0 ⇒ x - 5 = 0 ⇒ x = +5.
10. What is the oxidation state of Oxygen in OF₂ (Oxygen Difluoride)?
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Answer: A. +2
Explanation: Fluorine is more electronegative than oxygen (-1 each), forcing oxygen to exhibit a +2 oxidation state.
11. In the reaction CuO + H₂ → Cu + H₂O, the reducing agent is:
A. H₂
B. CuO
C. Cu
D. H₂O
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Answer: A. H₂
Explanation: H₂ gains oxygen (loses electrons) and gets oxidized from 0 to +1 state, making it the reducing agent.
12. What is the oxidation number of Iron (Fe) in Fe₃O₄?
A. +8/3
B. +2
C. +3
D. +6
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Answer: A. +8/3
Explanation: Fe₃O₄ is a mixed oxide (FeO·Fe₂O₃); average oxidation state is 3x + 4(-2) = 0 ⇒ x = +8/3.
13. In a Galvanic cell, oxidation takes place at the:
A. Anode
B. Cathode
C. Salt bridge
D. Electrolyte solution
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Answer: A. Anode
Explanation: In all electrochemical cells, oxidation always occurs at the anode electrode.
14. What is the main function of a salt bridge in an electrochemical cell?
A. Maintains electrical neutrality of both half-cells
B. Allows movement of electrons
C. Increases voltage output
D. Prevents mixing of gases
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Answer: A. Maintains electrical neutrality of both half-cells
Explanation: A salt bridge allows ion migration between half-cells to complete the circuit and maintain charge neutrality.
15. What is the oxidation state of Carbon in C₆H₁₂O₆ (Glucose)?
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Answer: A. 0
Explanation: 6x + 12(+1) + 6(-2) = 0 ⇒ 6x = 0 ⇒ x = 0.
16. Standard Hydrogen Electrode (SHE) is assigned a standard electrode potential of:
A. 0.00 V
B. 1.00 V
C. -1.00 V
D. 0.059 V
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Answer: A. 0.00 V
Explanation: By convention, standard reduction potential of SHE is defined as zero volts at all temperatures.
17. Which of the following elements exhibits only a single negative oxidation state in its compounds?
A. Fluorine
B. Oxygen
C. Chlorine
D. Nitrogen
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Answer: A. Fluorine
Explanation: Fluorine is the most electronegative element and always shows an oxidation state of -1 in its compounds.
18. What is the oxidation number of Chlorine (Cl) in CaOCl₂ (Bleaching powder)?
A. -1 and +1
B. +2 and -2
C. 0
D. +1 only
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Answer: A. -1 and +1
Explanation: CaOCl₂ is composed of Ca²⁺, Cl⁻ (-1 state), and OCl⁻ (+1 state for chlorine).
19. In acidic medium, KMnO₄ acts as a strong oxidizing agent and reduces to:
A. Mn²⁺
B. MnO₂
C. MnO₄²⁻
D. Mn³⁺
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Answer: A. Mn²⁺
Explanation: In acidic solution, MnO₄⁻ (+7) accepts 5 electrons to form colorless Mn²⁺ (+2).
20. Which of the following is NOT a redox reaction?
A. AgNO₃ + NaCl → AgCl + NaNO₃
B. 2H₂ + O₂ → 2H₂O
C. Zn + 2HCl → ZnCl₂ + H₂
D. CH₄ + 2O₂ → CO₂ + 2H₂O
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Answer: A. AgNO₃ + NaCl → AgCl + NaNO₃
Explanation: Double displacement/precipitation reactions involve no change in oxidation numbers of any element.
21. What is the oxidation state of Nitrogen in NH₄NO₃ (Ammonium Nitrate)?
A. -3 and +5
B. -3 only
C. +5 only
D. +1 and +3
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Answer: A. -3 and +5
Explanation: NH₄NO₃ contains NH₄⁺ (Nitrogen = -3) and NO₃⁻ (Nitrogen = +5).
22. The species having the highest reducing power has the:
A. Most negative reduction potential
B. Most positive reduction potential
C. Zero reduction potential
D. Highest oxidation state
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Answer: A. Most negative reduction potential
Explanation: A more negative reduction potential means a stronger tendency to lose electrons and act as a reducing agent.
23. What is the oxidation state of Chlorine in HClO₄ (Perchloric acid)?
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Answer: A. +7
Explanation: In HClO₄: (+1) + x + 4(-2) = 0 ⇒ x - 7 = 0 ⇒ x = +7.
24. What is the oxidation state of Hydrogen in Metal Hydrides like NaH?
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Answer: A. -1
Explanation: Hydrogen is more electronegative than alkali metals, accepting an electron to adopt a -1 oxidation state.
25. In neutral or weakly alkaline medium, KMnO₄ reduces to:
A. MnO₂
B. Mn²⁺
C. MnO₄²⁻
D. Mn₂O₃
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Answer: A. MnO₂
Explanation: In neutral/faintly alkaline media, MnO₄⁻ accepts 3 electrons to form dark brown insoluble MnO₂ (+4 state).
26. Oxidation number of Sulfur in Sodium Thiosulfate (Na₂S₂O₃) is:
A. +2
B. +2.5
C. +6
D. +4
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Answer: A. +2
Explanation: In Na₂S₂O₃: 2(+1) + 2x + 3(-2) = 0 ⇒ 2x - 4 = 0 ⇒ x = +2 (average oxidation state).
27. Which method is commonly used to balance complex redox equations?
A. Ion-electron (Half-reaction) method
B. Trial and error method
C. Gravimetric method
D. Volumetric method
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Answer: A. Ion-electron (Half-reaction) method
Explanation: The ion-electron method splits redox reactions into oxidation and reduction half-reactions to balance mass and charge systematically.
28. What is the oxidation state of Xe in XeF₄?
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Answer: A. +4
Explanation: In XeF₄: x + 4(-1) = 0 ⇒ x = +4.
29. When H₂S gas is passed through acidic K₂Cr₂O₇ solution, color changes from orange to green due to formation of:
A. Cr³⁺ ions
B. Cr⁶⁺ ions
C. SO₂ gas
D. S²⁻ ions
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Answer: A. Cr³⁺ ions
Explanation: Dichromate ions (Cr₂O₇²⁻, orange) get reduced to green hydrated chromium ions (Cr³⁺).
30. What is the oxidation state of Nickel in Ni(CO)₄?
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Answer: A. 0
Explanation: Carbon monoxide (CO) is a neutral ligand (charge = 0), so the oxidation state of Nickel is 0.